Benz[c]octalen

An expedient new synthesis of benzo[c]octalene starting from the Diels-Alder adduct of benzocyclobutadiene to 7,8-dimethylenecycloocta-1,3,5-triene is described. This octalene derivative, in solution, exists as an equilibrating mixture of the double bond isomers (2) and (3) whereas in its crystalline state only the isomer (2) is present.     

Experimental verification of the optimal distribution of exposures in speckle coded image subtraction configurations

Subtracted images can be obtained by optical filtering of a composite record containing multiple exposures of the two scenes suitably encoded by a speckle pattern. An experiment has been carried out to compare the performance of such a system when the multiple exposures are related to each other by the binomial coefficients or by the optimal coefficients which are determined by the size of the filtering slit.     

Long-range critical wetting: observation of a critical end point

Alkanes deposited on aqueous substrates exhibit two different types of wetting behavior: alternatively to the usual first-order wetting transition, a sequential-wetting scenario of a long-range critical wetting transition preceded by a first-order thin-thick transition may be observed. Here, we present the first successful experimental attempt to locate the transition point between the standard first-order wetting and the long-range critical wetting: a critical end point, observed in a mixture of pentane and hexane which is deposited on an aqueous solution of glucose. Furthermore, we present the first direct measurement of the contact angle in the intermediate wetting state (frustrated-complete wetting) in the sequential-wetting scenario of hexane on brine and compare to theoretical predictions.     

Nuclear magnetic resonance-compatible furnace for high temperature MR imaging and spectroscopy in situ

A high temperature magnetic resonance compatible furnace for real time in situ monitoring of materials, processes, and chemical reactions with magnetic resonance imaging and spectroscopy is described. Design issues are analyzed. Example applications are demonstrated with a time sequence of proton images of the binder burnout in a porous green ceramic cylinder containing polyethylene glycol binder at 200 degrees C, and 7Li images of the molten salt LiCl at 700 degrees C.     

Simultaneous multicolor image formation with a single diffractive optical element

A design for a novel diffractive optical element (DOE) that can reconstruct three different intensity patterns when it is illuminated by three different wavelengths is presented. If the chosen wavelengths are red, green, and blue, full-color reconstruction capability is obtained. Reconstruction is achieved in the near field (Fresnel domain). Computer simulation results as well as experimental evidence are presented, proving the capabilities of this novel DOE design procedure.